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Waterborne polyurethane composite coatings as UV-light converter and directional infrared light barrier for light and heat management in greenhouse

文献类型： 外文期刊

作者： Wang, Jie 1 ; Gao, Changzhou 4 ; Fang, Jiaojiao 5 ; Fang, Liang 1 ; Lu, Chunhua 1 ; Xu, Zhongzi 1 ;

作者机构： 1.Nanjing Tech Univ, Coll Mat Sci & Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China

2.Nanjing Tech Univ, Jiangsu Collaborat Innovat Ctr Adv Inorgan Funct C, Nanjing 210009, Peoples R China

3.Nanjing Tech Univ, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, Nanjing 210009, Peoples R China

4.Jiangsu Acad Agr Sci, Inst Vegetable, Nanjing 210014, Peoples R China

5.Anhui Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Mol Solids, Minist Educ, Wuhu 241002, Peoples R China

关键词： Rare-earth organic complexes; Waterborne polyurethane; Down-conversion; Agricultural films

期刊名称：PROGRESS IN ORGANIC COATINGS （ 影响因子：6.6； 五年影响因子：5.9 ）

ISSN： 0300-9440

年卷期： 2023 年 183 卷

页码：

收录情况： SCI

摘要： Light and heat management in greenhouses are important for crops yield and quality. Here, we created waterborne polyurethane (WPU) composite coatings for greenhouse films, which can act both as ultraviolet (UV) light down-conversion and directional infrared light barrier for the light and temperature conditions in pepper greenhouses. Rare-earth organic complexes (REOC) that can convert UV light to red light were mixed with WPU by ball-milling. The REOC nanoparticles presented good dispersion in WPU coatings, which were determined by atomic force microscopy, and the coating with 1 wt% REOC still remained comparably high transparency. The luminescence properties were increased with REOC loadings. The coatings with REOC showed lower infrared (IR) light transmittance and higher IR light reflectance than those of the pristine film and WPU coatings. The preferable location of the composite coatings on inner side of films acted as IR light barrier and facilitated the maintenance of heat inside the greenhouses, increasing the temperature. Simulation was performed to testify the temperature increase using IR barrier covered layer. Small and big greenhouses with different films were built and the temperatures were recorded. The results show that the film containing REOC increase the temperature in the greenhouses by >2 degrees C compared to traditional agricultural films. Finally, due to light conversion and IR light barrier, the yields of green peppers can be increased by 35 %. The mass of single fruits can also be increased by 8 g.

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