文献类型: 外文期刊
作者: Zhang, Wenhao 1 ; Liu, Guiru 1 ; Cao, Jing 1 ; Chen, Yuanyuan 2 ; Gao, Lei 1 ; Liu, Guanghua 1 ; Dai, Gaole 2 ; Wang, Qing 1 ;
作者机构: 1.Inner Mongolia Univ, Sch Chem & Chem Engn, 235 West Univ St, Hohhot 010021, Peoples R China
2.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Coll Mat Chem & Chem Engn, 2318 Yuhangtang Rd, Hangzhou 311121, Zhejiang, Peoples R China
3.Inner Mongolia Acad Agr & Anim Husb Sci, Inst Environm Resources & Analyt Tech, Zhao Jun Rd, Hohhot 010031, Peoples R China
关键词: Aromaticity; BN doping; Dual emission; Lewis acidity; Polycyclic aromatic hydrocarbons
期刊名称:CHEMISTRY-AN ASIAN JOURNAL ( 影响因子:4.839; 五年影响因子:4.244 )
ISSN: 1861-4728
年卷期: 2022 年 17 卷 15 期
页码:
收录情况: SCI
摘要: A B-N embedded nitrogen-annulated perylene has been successfully synthesized. The resultant molecule BN-NP is isoelectronic to coronene, but owns a five-membered pyrrole ring. Experiments and DFT calculations indicated that peripheral pyrrole and BN modifications endow BN-NP with various unique properties like bent structure, dual emission, efficient Lewis acidic response, peripheral aromaticity, narrowest energy band gap among all coronene isoelectronic structures and so on.
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