Magnetic metal-organic frameworks as adsorbents for the detection of azo pigments in food matrices
文献类型: 外文期刊
作者: Cheng, Lei 1 ; Huang, Rong 1 ; Cao, Qiang 2 ; Liu, Na 2 ; Li, Peiyi 2 ; Sun, Mengmeng 2 ; Qin, Haiyang 2 ; Wu, Lidong 2 ;
作者机构: 1.Beijing Technol & Business Univ BTBU, Beijing Engn & Technol Res Ctr Food Addit, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
2.Chinese Acad Fishery Sci, Key Lab Control Qual & Safety Aquat Prod, Minist Agr & Rural Affairs, Beijing 100141, Peoples R China
3.Shanghai Ocean Univ, Coll Food Sci & Technol, Shanghai 201306, Peoples R China
关键词: Selective separation; New coccine; Lemon yellow; HPLC-MS
期刊名称:FOOD CHEMISTRY ( 影响因子:8.8; 五年影响因子:8.6 )
ISSN: 0308-8146
年卷期: 2023 年 402 卷
页码:
收录情况: SCI
摘要: Azo pigments with azo functional groups (-N--N-) are commonly used in foods. Through rational design, here we report synthesis of a novel magnetic metal-organic framework (MOF-545) and the use of Fe3O4@MOF-545 for the selective separation of azo pigments from beverages. We find that Fe3O4@MOF-545 exhibits excellent adsorption/removal capacities for new coccine (NC, 459 mg g-1) and lemon yellow (LY, 476 mg g-1) individ-ually. The results indicated that the adsorption capacities of Fe3O4@MOF-545 were 5 times higher than reported previously. The large surface area (120.4 m2/g) and the suitable pore size (1.6 nm) of Fe3O4@MOF-545 provided multiple accessible channels for azo pigment adsorption. The adsorption kinetics, stability, recovery, and reus-ability of Fe3O4@MOF-545 were all reported. The recoveries ranged from 92.9 to 104.5%, reflecting the capacity of MOF-545 to efficiently separate NC and LY. Fe3O4@MOF-545 is suitable for azo pigment determination and separation in food matrices.
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