WATER COMPATIBLE MOLECULARLY IMPRINTED POLYMER MICROSPHERES FOR EXTRACTION OF AMPICILLIN IN FOODS
文献类型: 外文期刊
作者: Shi, Xizhi 1 ; Song, Suquan 1 ; Qu, Guorun 1 ; Zheng, Sulian 1 ; Wu, Aibo 1 ; Zhang, Dabing 1 ;
作者机构: 1.Shanghai Jiao Tong Univ, Sch Life Sci & Biotechnol, Bor Luh Food Safety Ctr, Shanghai 200240, Peoples R China
2.Ningbo Univ, Minist Educ, Key Lab Appl Technol Marine Biol, Ningbo, Peoples R China
3.Shanghai Acad Agr Sci, Inst Agri Food Stand & Testing Technol, Shanghai, Peoples R China
关键词: Ampicillin;Molecularly imprinted polymer microspheres;Solid-phase extraction
期刊名称:ANALYTICAL LETTERS ( 影响因子:2.329; 五年影响因子:1.738 )
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收录情况: SCI
摘要: The ampicillin (AMPI) molecularly imprinted polymer microspheres (MIPMs) via aqueous suspension polymerization were synthesized for the first time. Evaluation on the MIPMs by chromatographic analysis indicated that the optimum type and ratio of functional monomer to the template was 2-(Diethylamino) ethyl methacrylate (DEAEM) and 8:1, respectively. Under the optimized MISPE conditions, the recoveries were all above 89% for spiked AMPI in honey samples. After MISPE treatment, the obtained AMPI chromatograms showed that the matrix interferences could be almost neglected. The results demonstrate that the obtained MIPMs are applicable as inner adsorbents in MISPE cartridges for extraction of AMPI in foods.
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