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High Efficient Visible-Light Photocatalytic Performance of Cu/ZnO/rGO Nanocomposite for Decomposing of Aqueous Ammonia and Treatment of Domestic Wastewater

文献类型： 外文期刊

作者： He, Shiying 1 ; Hou, Pengfu 1 ; Petropoulos, Evangelos 2 ; Feng, Yanfang 1 ; Yu, Yingliang 1 ; Xue, Lihong 1 ; Yang, L 1 ;

作者机构： 1.Jiangsu Acad Agr Sci, Inst Agr Resources & Environm, Nanjing, Jiangsu, Peoples R China

2.Newcastle Univ, Sch Engn, Newcastle Upon Tyne, Tyne & Wear, England

关键词： ZnO; graphene oxide; nanocomposite; photocatalysis; ammonia-nitrogen removal; water treatment

期刊名称：FRONTIERS IN CHEMISTRY （ 影响因子：5.221； 五年影响因子：5.385 ）

ISSN： 2296-2646

年卷期： 2018 年 6 卷

页码：

收录情况： SCI

摘要： Photocatalytic removal of ammonium nitrogen (NH N) from water using solar energy is an approach of high interest and applicability due to the convenience in application. ZnO has a great potential in photocatalytic decomposition of NI-1-N and conversion of this nutrient to under visible light irradiations. However the applicability of pristine ZnO though is limited due to its reduced capacity to utilize light from natural light. Herein, we report a two-step ZnO -modified strategy (Cu-doped ZnO nanoparticles, immobilized on reduced graphene oxide (rGO) sheets) for the promotion of photocatalytic degradation of NH4+-N under visible light. UV-Vis spectra showed that the Cu/ZnO/rGO can be highly efficient in the utilization of photons from the visible region. Hence, Cu/ZnO/rGO managed to demonstrate adequate photocatalytic activity and effective NI-Cr-N removal from water under visible light compared to single ZnO. Specifically, up to 83.1% of NHI-N (initial concentration 50 mg.L-1,catalyst dosage 2 g.L-1, pH 10) was removed within 2 h retention time under Xe lamp irradiation. From the catalysis, the major by-product was N-2. The high ammonia degradation efficiency from the ZnO/Cu/rGO is attributed to the improvement of the reactive oxygen species (ROSs) production efficiency and the further activation of the interfacial catalytic sites. This study also demonstrated that such nanocomposite is a recyclable agent. Its NI-1-N removal capacity remained effective even after five batch cycles. In addition, Cu/ZnO/rGO was applied to treat real domestic wastewater, and it was found that chemical oxygen demand (COD), total nitrogen (TN) and total phosphorus (TP) removal efficiencies can reach 84.3, 80.7, and 90.3%, respectively. Thus, Cu/ZnO/rGO in the presence of solar light can be a promising photocatalyst in the field of wastewater treatment.

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