您好,欢迎访问中国水产科学研究院 机构知识库!

In situ Growth of Cu2O/CuO Nanosheets on Cu Coating Carbon Cloths as a Binder-Free Electrode for Asymmetric Supercapacitors

文献类型: 外文期刊

作者: Xu, Lina 1 ; Li, Jiao 1 ; Sun, Haibin 1 ; Guo, Xue 1 ; Xu, Jiakun 2 ; Zhang, Hua 1 ; Zhang, Xiaojiao 1 ;

作者机构: 1.Shandong Univ Technol, Sch Mat Sci & Engn, Zibo, Peoples R China

2.Chinese Acad Fishery Sci, Yellow Sea Fisheries Res Inst, Qingdao, Shandong, Peoples R China

关键词: copper oxide; nanostructures; electrode; carbon cloth; asymmetric supercapacitor

期刊名称:FRONTIERS IN CHEMISTRY ( 影响因子:5.221; 五年影响因子:5.385 )

ISSN: 2296-2646

年卷期: 2019 年 7 卷

页码:

收录情况: SCI

摘要: Cu2O/CuO nanosheets in-situ grown on Cu-Carbon cloths (Cu-CCs), namely Cu2O/CuO@Cu-CCs, are constructed by a simple strategy with electroless copper plating, chemical etching, and thermal dehydration. The as-prepared material is directly used as binder-free electrodes for supercapacitors (SCs). CCs coated with Cu, as the current collector, can effectively promote the charge collection and electron transfer, while the hierarchical Cu2O/CuO nanosheets provide massive active sites for fast faradic reactions. The composite electrode exhibits high specific capacitance [1.71 F cm(-2), equivalent to 835.2 F g(-1), at the current density of 10 mA cm(-2) (3.57 A g(-1))]. The asymmetric supercapacitor device using Cu2O/CuO@Cu-CCs as the positive electrode and activated carbon as the negative electrode, achieves a superior energy density up to 60.26 Wh kg(-1) at a power density of 299.73 W kg(-1) and an excellent long-term cycling stability (9.65% loss of its initial capacitance after 5,000 cycles). The excellent electrochemical performance is mainly ascribed to the unique hierarchical structure of Cu2O/CuO@Cu-CCs, making it attractive as a potential electrode material for high performance SCs.

  • 相关文献
作者其他论文 更多>>