Simultaneous Determination of Seven Pesticides and Metabolite Residues in Litchi and Longan through High-Performance Liquid Chromatography-Tandem Mass Spectrometry with Modified QuEChERS
文献类型： 外文期刊
作者： Wang, Siwei 1 ; Wang, Xiaonan 1 ; He, Qiang 3 ; Lin, Haidan 3 ; Chang, Hong 1 ; Sun, Haibin 1 ; Liu, Yanping 1 ;
作者机构： 1.Guangdong Acad Agr Sci, Key Lab Green Prevent & Control Fruits & Vegetabl, South China Minist Agr & Rural Affairs, Inst Plant Protect,Guangdong Prov Key Lab High Te, Guangzhou 510640, Peoples R China
2.South China Agr Univ, Guangdong Engn Res Ctr Insect Behav Regulat, Guangzhou 510642, Peoples R China
3.Guangdong Qual Safety Ctr Agr Prod, Dept Agr & Rural Affairs Guangzhou, Guangzhou 510230, Peoples R China
关键词： QuEChERS; HPLC-MS; MS; litchi and longan; pesticide and metabolite; residue
期刊名称：MOLECULES （ 影响因子：4.927； 五年影响因子：5.11 ）
ISSN：
年卷期： 2022 年 27 卷 17 期
页码：
收录情况： SCI
摘要： This study established a QuEChERS high-performance liquid chromatography/tandem triple-quadrupole mass spectrometry method for determining azoxystrobin, pyraclostrobin, picoxystrobin, difenoconazole, chlorantraniliprole, imidacloprid, and cyantraniliprole and its metabolite (IN-J9Z38) in litchi and longan, and applied this method to the real samples. The residues in samples were extracted with acetonitrile and purified with nano-ZrO2, C-18, and PSA. The samples were then detected with multireactive ion monitoring and electrospray ionization in the positive ion mode and quantified using the external matrix-matched standard method. The results showed good linearities for the eight analytes in the range of 1-100 mu g/L, with correlation coefficients (r(2)) of >0.99. The limit of quantification was 1-10 mu g/kg, and the limit of detection was 0.3-3 mu g/kg. Average recovery from litchi and longan was 81-99%, with the relative standard deviation of 3.5-8.4% at fortified concentrations of 1, 10, and 100 mu g/kg. The developed method is simple, rapid, efficient, and sensitive. It allowed the rapid screening, monitoring, and confirming of the aforementioned seven pesticides and a metabolite in litchi and longan.
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