Dissipation and Safety Analysis of Dimethomorph Application in Lychee by High-Performance Liquid Chromatography-Tandem Mass Spectrometry with QuEChERS
文献类型： 外文期刊
作者： Wang, Siwei 1 ; Wang, Xiaonan 1 ; Liu, Yanping 1 ; He, Qiang 2 ; Tian, Hai 3 ;
作者机构： 1.Guangdong Acad Agr Sci, Plant Protect Res Inst, Key Lab Green Prevent & Control Fruits & Vegetable, Minist Agr & Rural Affairs,Guangdong Prov Key Lab, 7 Jinying Rd Tianhe Dist, Guangzhou 510640, Peoples R China
2.Guangdong Qual Safety Ctr Agr Prod, Guangdong Green Food Dev Ctr, Dept Agr & Rural Affairs Guangzhou, 135 Xianlie East Rd Tianhe Dist, Guangzhou 510500, Peoples R China
3.Chinese Acad Trop Agr Sci, Anal & Testing Ctr, Key Lab Qual & Safety Control Subtrop Fruits & Veg, Minist Agr & Rural Affairs, 4 Xueyuan Rd,Longhua Dist, Haikou 571101, Peoples R China
关键词： dimethomorph; lychee; terminal residues; dissipation dynamic; risk quotient
期刊名称：MOLECULES （ 影响因子：4.6； 五年影响因子：4.9 ）
ISSN：
年卷期： 2024 年 29 卷 8 期
页码：
收录情况： SCI
摘要： This study presents a method for analyzing dimethomorph residues in lychee using QuEChERS extraction and HPLC-MS/MS. The validation parameters for this method, which include accuracy, precision, linearity, and recovery, indicate that it meets standard validation requirements. Following first-order kinetics, the dissipation dynamic of dimethomorph in lychee was determined to range from 6.4 to 9.2 days. Analysis of terminal residues revealed that residues in whole lychee were substantially greater than those in the pulp, indicating that dimethomorph residues are predominantly concentrated in the peel. When applied twice and thrice at two dosage levels with pre-harvest intervals (PHIs) of 5, 7, and 10 days, the terminal residues in whole lychee ranged from 0.092 to 1.99 mg/kg. The terminal residues of the pulp ranged from 0.01 to 0.18 mg/kg, with the residue ratio of whole lychee to pulp consistently exceeding one. The risk quotient (RQ) for dimethomorph, even at the recommended dosage, was less than one, indicating that the potential for damage was negligible. This study contributes to the establishment of maximum residue limits (MRLs) in China by providing essential information on the safe application of dimethomorph in lychee orchards.
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