Synthesis of fungicidal morpholines and isochromenopyridinones via acid-catalyzed intramolecular reactions of isoindolinones
文献类型： 外文期刊
作者： Liu, Xiaoyu 1 ; Sun, Yaru 1 ; Hong, Shuang 1 ; Ji, Xia 1 ; Gao, Wei 1 ; Yuan, Haolin 1 ; Zhang, Yue 1 ; Lei, Bin 2 ; Tang, Liangfu 1 ; Fan, Zhijin 1 ;
作者机构： 1.Nankai Univ, Coll Chem, State Key Lab Elemento Organ Chem, Tianjin 300071, Peoples R China
2.Xinjiang Acad Agr Sci, Pesticide Prod & Expt Ctr, Urumqi 830091, Peoples R China
3.Nankai Univ, Coll Chem, Frontiers Sci Ctr New Organ Matter, Tianjin 300071, Peoples R China
期刊名称：ORGANIC & BIOMOLECULAR CHEMISTRY （ 影响因子：3.2； 五年影响因子：3.0 ）
ISSN： 1477-0520
年卷期： 2023 年
页码：
收录情况： SCI
摘要： Acid-catalyzed intramolecular cyclization or rearrangement of isoindolinone derivatives is described. 3-Hydroxy/ethoxy-3,4-dihydro-6H-[1,4]-oxazino-[3,4-a]-isoindol-6-ones are obtained in moderate to good yields. Further acid-catalyzed intramolecular rearrangement reactions give 6H-isochromeno-[4,3-b]-pyridin-6-ones. The mild reaction conditions with convenient starting materials show broad substrate scope and provide the target compounds as novel pesticide leads with good fungicidal or systemical acquired resistance activities.
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