Molecularly imprinted solid-phase extraction coupled with HPLC for the selective determination of monobutyl phthalate in bottled water
文献类型： 外文期刊
作者： Qi, Peipei 1 ; Wang, Jincheng 1 ; Li, Yun 1 ; Su, Fan 1 ; Jin, Jing 1 ; Chen, Jiping 1 ;
作者机构： 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Zhejiang Acad Agr Sci, Inst Qual & Standard Agroprod, Hangzhou, Zhejiang, Peoples R China
关键词： Bottled water;Molecularly imprinted polymer;Monobutyl phthalate;Selective solid-phase extraction
期刊名称：JOURNAL OF SEPARATION SCIENCE （ 影响因子：3.645； 五年影响因子：2.943 ）
ISSN：
年卷期：
页码：
收录情况： SCI
摘要： A molecularly imprinted polymer (MIP) was prepared using monobutyl phthalate as template. The synthesis was optimized by using different porogens and functional monomers. The MIP was used as a selective sorbent in molecularly imprinted solid-phase extraction (MIP-SPE) for pre-concentration and determination of monobutyl phthalate (mBP) from the bottled water. The difference in recognition selectivity of the polymer columns was observed in HPLC system, and the effect of the mobile phase on the performance of MIP columns was also investigated. Control of the MIP-SPE process is seen as important in helping to facilitate the selective extraction of mBP from water samples. Thereafter, the choice of washing solvent, eluting solvent amount, pH of loading sample, flow rate of loading solution and the loading sample volume was presented. The optimized procedure was described as follows: 25mL spiked aqueous solution was percolated through the MIP-SPE cartridge at the flow rate of 1.5mL/min. After rinsing with acetonitrile/methanol mixture (1:1, v/v), the bound analyte was desorbed with 3mL methanol. The developed MIP-SPE method was demonstrated to be applicable for the analysis of mBP in the bottled water.
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