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Enantioselective degradation of tebuconazole in cabbage, cucumber, and soils

文献类型： 外文期刊

作者： Wang, Xinquan 1 ; Wang, Xuesong 2 ; Zhang, Hu 1 ; Wu, Changxing 1 ; Wang, Xiangyun 1 ; Xu, Hao 1 ; Wang, Xiaofu 1 ; Li, Z 1 ;

作者机构： 1.Zhejiang Acad Agr Sci, Inst Qual & Stand Agr Prod, State Key Lab Breeding Base Zhejiang Sustainable, Hangzhou 310021, Zhejiang, Peoples R China

2.NE Agr Un

关键词： Cabbage;Cucumber;Degradation;Enantioselective;Soil;Tebuconazole

期刊名称：CHIRALITY （ 影响因子：2.437； 五年影响因子：2.204 ）

ISSN：

年卷期：

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收录情况： SCI

摘要： The enantioselective degradation of tebuconazole has been investigated to elucidate the behaviors in agricultural soils, cabbage, and cucumber fruit. Rac-tebuconazole was fortified into three types of agricultural soils and sprayed foliage of cabbage and cucumber, respectively. The degradation kinetics, enantiomer fraction and enantiomeric selectivity were determined by reverse-phase high-performance liquid chromatography (HPLC) and liquid chromatography- mass spectrometry/mass spectrometry (LC-MS/MS) on a Lux amylose-2 chiral column. The process of the degradation of tebuconazole enantiomers followed first-order kinetic in the test soils and vegetables. It has been shown that the degradation of tebuconazole was enantioselective. The results indicated that the (+)-S-tebuconazole showed a faster degradation in cabbage, while the (-)-R-tebuconazole dissipated faster than (+)-S-form in cucumber fruit and the test soils.

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