Hydrothermal synthesis, crystal structures, and photoluminescent properties of two cadmium(II) coordination polymers derived from dicarboxylates and N-donor ligands
文献类型： 外文期刊
作者： Xu, Jiakun 1 ; Sun, Xiaochun 3 ; Ju, Caixia 1 ; Yang, Lirong 5 ; Bi, Caifeng 2 ; Sun, Mi 1 ;
作者机构： 1.Chinese Acad Fishery Sci, Yellow Sea Fisheries Res Inst, Qingdao, Peoples R China
2.Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao, Peoples R China
3.Natl Oceanog Ctr, Qingdao, Peoples R China
4.Shanghai Ocean Univ, Coll Food Sci & Technol, Shanghai, Peoples R China
5.Henan Univ, Coll Chem & Chem Engn, Kaifeng, Peoples R China
关键词： Cd coordination polymers;Crystal structures;Luminescent properties
期刊名称：JOURNAL OF COORDINATION CHEMISTRY （ 影响因子：1.751； 五年影响因子：1.462 ）
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年卷期：
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收录情况： SCI
摘要： Two metal coordination polymers, [Cd(ipa)(L])(H_2O)]_n (1) and [Cd(ipa)(L_2)]_n (2) [H_2ipa=isophthalic acid, L_1 = 3,5-bis(imidazole-l-yl)pyridine and L_2 = 3,5-bis(benzoimidazo-l-ly)pyridine], have been synthesized and structurally characterized by IR, elemental analysis, XRD, and X-ray single-crystal diffraction. Complex 1 shows a twofold cds topological net and 2 features a 3-D pcu topological net. Luminescent properties of 1 and 2 were investigated in the solid state at room temperature.
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