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Degradation of three fungicides following application on strawberry and a risk assessment of their toxicity under greenhouse conditions

文献类型： 外文期刊

作者： Sun, Caixia 1 ; Cang, Tao 1 ; Wang, Zhiwei 1 ; Wang, Xinquan 1 ; Yu, Ruixian 1 ; Wang, Qiang 2 ; Zhao, Xueping;

作者机构： 1.Zhejiang Acad Agr Sci, State Key Lab Breeding Base Zhejiang Sustainable, MOA Key Lab Pesticide Residue Detect, Inst Qual & Standard Agroprod, Hangzhou, Zhejiang, Peoples R China

2.Zhejiang Acad Agr Sci, State Key Lab Breeding Base Zhejiang Sustainable, MOA Key Lab Pesticide Residue Detect, Inst Qual & Standa

关键词： Pyraclostrobin;Myclobutanil;Difenoconazole;Strawberry;Safety evaluation

期刊名称：ENVIRONMENTAL MONITORING AND ASSESSMENT （ 影响因子：2.513； 五年影响因子：2.871 ）

ISSN：

年卷期：

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收录情况： SCI

摘要： The health risk to humans of pesticide application on minor crops, such as strawberry, requires quantification. Here, the dissipation and residual levels of three fungicides (pyraclostrobin, myclobutanil, and difenoconazole) were studied for strawberry under greenhouse conditions using high-performance liquid chromatography (HPLC)-tandem mass spectrometry after Quick, Easy, Cheap, Effective, Rugged, and Safe extraction. This method was validated using blank samples, with all mean recoveries of these three fungicides exceeding 80 %. The residues of all three fungicides dissipated following first-order kinetics. The half-lives of pyraclostrobin, myclobutanil, and difenoconazole were 1.69, 3.30, and 3.65 days following one time application and 1.73, 5.78, and 6.30 days following two times applications, respectively. Fungicide residue was determined by comparing the estimated daily intake of the three fungicides against the acceptable daily intake. The results indicate that the potential health risk of the three fungicides was not significant in strawberry when following good agricultural practices (GAP) under greenhouse conditions.

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