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Strengthened Removal of Tetracycline by a Bi/Ni Co-Doped SrTiO3/TiO2 Composite under Visible Light

文献类型： 外文期刊

作者： Chen, Weifang 1 ; Zhao, Na 1 ; Hu, Mingzhu 1 ; Liu, Xingguo 2 ; Deng, Baoqing 1 ;

作者机构： 1.Univ Shanghai Sci & Technol, Sch Environm & Architecture, Shanghai 200093, Peoples R China

2.Chinese Acad Fishery Sci, Fishery Machinery & Instrument Res Inst, 63 Chifeng Rd, Shanghai 200092, Peoples R China

关键词： SrTiO3/TiO2; dope; Bi/Ni; photocatalytic; tetracycline

期刊名称：CATALYSTS （ 影响因子：4.0； 五年影响因子：4.0 ）

ISSN：

年卷期： 2024 年 14 卷 8 期

页码：

收录情况： SCI

摘要： A two-step hydrothermal method was used to first obtain a SrTiO3/TiO2 composite then to dope the composite with Bi, Ni and Bi/Ni. Morphology, crystalline structures, surface valances and optical features of SrTiO3/TiO2 and Bi-, Ni-, Bi/Ni-doped SrTiO3/TiO2 were assessed. XRD and XPS analysis showed that Bi and Ni were successfully doped and existed in Bi(3+) and Ni(2+) oxidation state. UV-vis analysis further revealed that the bandgap energies of TiO2 and SrTiO3/TiO2 were calculated to be 3.14 eV and 3.04 eV. By comparison, Bi, Ni and Bi/Ni doping resulted in the narrowing of bandgaps to 2.82 eV, 2.96 eV and 2.69 eV, respectively. The removal ability of SrTiO3/TiO2 and doped SrTiO3/TiO2 were investigated with tetracycline as the representative pollutant. After 40 min of exposure to visible light, Bi/Ni co-doped SrTiO3/TiO2 photocatalyst was able to remove 90% of the tetracycline with a mineralization rate of about 70%. In addition, first-order removal rate constant was 0.0074 min(-1) for SrTiO3/TiO2 and increased to 0.0278 min(-1) after co-doping. The strengthened removal by co-doped photocatalyst was attributed mainly to the enhanced absorption of visible light as co-doping resulted in the decreases of bandgap energies. At the same time, the co-doped material was robust against changes in pH. Removal of tetracycline was stable as pH changed from 5 to 9. Tetracycline removal was inhibited to a certain degree by the presence of nitrate, phosphate and high concentration of humic acid. Moreover, the co-doped material exhibited strong structural stability and reusability. In addition, a photocatalysis mechanism with photogenerated holes and O-2(-) radicals as main oxidative species was proposed based on entrapping experiments and EPR results.

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