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Evaluation of chiral triticonazole in three kinds of fruits: enantioseparation, degradation, and dietary risk assessment

文献类型： 外文期刊

作者： Guo, Chao 1 ; Di, Shanshan 2 ; Chen, Xiaolong 1 ; Wang, Yanhua 2 ; Qi, Peipei 2 ; Wang, Zhiwei 2 ; Zhao, Huiyu 2 ; Gu, Yuanlin 2 ; Xu, Hao 2 ; Lu, Yuele 1 ; Wang, Xinquan 2 ;

作者机构： 1.Zhejiang Univ Technol, Coll Biotechnol & Bioengn, Inst Fermentat Engn, Hangzhou 310032, Peoples R China

2.Zhejiang Acad Agr Sci, Inst Agroprod Safety & Nutr, State Key Lab Managing Biot & Chem Threats Qual &, Key Lab Detect Pesticide Residues & Control Zheji, Hangzhou 310021, Peoples R China

3.Northeast Agr Univ, Coll Agr, 600 Changjiang Rd, Harbin 150030, Peoples R China

关键词： Chiral triticonazole; Fruits; SFC-MS/MS; Enantioseparation; Enantioselective degradation; Dietary risk assessment

期刊名称：ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH （ 影响因子：5.19； 五年影响因子：5.053 ）

ISSN： 0944-1344

年卷期： 2022 年 29 卷 22 期

页码：

收录情况： SCI

摘要： The enantioselective behaviors of chiral pesticides would affect the accuracy of risk assessment. This study evaluated the enantioselectivity of chiral triticonazole (a widely used fungicide) in three kinds of fruits. Firstly, the enantioseparation of triticonazole enantiomers was carried out within 1.2 min utilizing CHIRALPAK OJ-3 column with a mixture of CO2 and methanol (93:7, v/v) using SFC-MS/MS. Secondly, field trials were conducted to clarify the enantioselective degradation and residue of S-(+)-triticonazole and R-(-)-triticonazole in fruits. The initial concentrations of rac-triticonazole were 25.1-93.1 ng/g, and enantioselective degradation was observed in pear, peach, and jujube after 2 h, 10 days, and 3 days, respectively. The degradation of S-( +)-triticonazole was fastest in pear (T-1/2, 2.01 days), while the T-1/2 of R-(-)-triticonazole was 5.02 days. The residue concentrations of rac-triticonazole were less than the MRL set by EU (10 ng/g) on the 3rd and 21st day in pear and peach, respectively, which were lower than 10 ng/g in jujube on the 30th day (no MRL). Finally, we found that the dietary intake risks of rac-triticonazole in fruits were low for 2-7 age, 20-50 age/female, and 20-50 age/male. The current study could provide complimentary references for the rational usage, MRL formulation, and risk assessment of chiral triticonazole.

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