文献类型： 外文期刊

作者： Yao, Youru ¹ ; Zhang, Jingyi ¹ ; Ma, Kang ¹ ; Li, Jing ² ; Hu, Xin ³ ; Wang, Yusi ¹ ; Lin, Yuesheng ¹ ; Fang, Fengman ¹ ; Li, Shiyin ⁴ ;

作者机构： 1.Anhui Normal Univ, Sch Geog & Tourism, Key Lab Earth Surface Proc & Reg Response Yangtze, Wuhu 241002, Anhui, Peoples R China

2.Jiangsu Acad Agr Sci, Inst Agr Resources & Environm, Key Lab Agroenvironm Downstream Yangtze Plain, Natl Agr Expt Stn Agr Environm, Nanjing 210014, Peoples R China

3.Nanjing Univ Aeronaut & Astronaut, Ctr Microscopy & Anal, Nanjing 210016, Peoples R China

4.Nanjing Normal Univ, Sch Environm, Nanjing 210023, Peoples R China

5.Jiangsu Ctr Collaborat Innovat Geog Informat Resou, Nanjing 210023, Peoples R China

关键词： dissolved organic matter; copper; combination mechanism; humic acid-like substances

期刊名称：AGRICULTURE-BASEL （ 影响因子：3.6； 五年影响因子：3.6 ）

ISSN：

年卷期： 2024 年 14 卷 5 期

页码：

收录情况： SCI

摘要： Dissolved organic matter (DOM) serves as a critical link in the migration and transformation of heavy metals at the soil-solid interface, influencing the migration behaviour and transformation processes of Cu2+ in soil. There have been studies on the combination mechanisms between DOM and Cu2+ in paddy soils. However, the adsorption/complexation and redox processes between DOM and Cu2+ in other agricultural soil types (such as dry farmland and vegetable fields) are unclear. In order to reveal the combination process of DOM with Cu in different agricultural soil types and the dynamic changes in chemical behaviour that occur, this study analysed the variability of DOM components and structure in three soils using three-dimensional fluorescence spectroscopy and X-ray photoelectron spectroscopy. In addition, the priority order of different DOM compounds in combination with Cu and the change process in relation to the Cu valence state in the soil of Lujiang County, Anhui Province, was revealed based on laboratory experiments. The results showed that the composition of soil DOM was mainly composed of humic-like and fulvic-like substances with a clear terrestrial origin and that the organic matter showed a high degree of decomposition characteristics. The results indicated that the composition of soil DOM is mainly composed of humic and fulvic acid-like substances, and they have obvious characteristics of terrestrial origin. In addition, the soil organic matter showed high decomposition characteristics. The complex stability constants (lgK(M)) of humic acid-like substances with Cu2+ follow the order of forest land (lgK(M) = 5.21), vegetable land (lgK(M) = 4.90), and dry farmland (lgK(M) = 4.88). The lgK(M) of fulvic acid-like substances with Cu2+ is in the order of dry farmland (lgK(M) = 4.51) and vegetable land (lgK(M) = 4.39). Humic acid-like substances in soil DOM combine preferentially with Cu2+, showing a stronger chelating affinity than fulvic acid-like substances. Cu2+ complexes mainly include hydroxyl, phenolic hydroxyl and amino functional groups are included in soil DOM, accompanied by redox reactions. In comparison to dry farmland, the soil DOM in forest and vegetable fields undergoes more intense redox reactions simultaneously with the chelation of Cu2+. Therefore, the application of organic fertilisers to vegetable and forest soils may lead to uncertainties concerning the fate of heavy metals with variable chemical valence. These results contribute to a deeper understanding of the interaction mechanisms between DOM and Cu2+ in agricultural soils.