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Synthesis, Crystal Structures and Luminescent Properties of pH-Dependent Zn (II) Coordination Polymers

文献类型： 外文期刊

作者： Xu, Jiakun 1 ; Sun, Xiaochun 3 ; Fan, Yuhua 2 ; Bi, Caifeng 2 ; Sun, Mi 1 ;

作者机构： 1.Chinese Acad Fishery Sci, Yellow Sea Fisheries Res Inst, Qingdao 266071, Peoples R China

2.Ocean Univ China, Key Lab Marine Chem Theory & Technol, Minist Educ, Qingdao 266100, Peoples R China

3.Natl Oceanog Ctr, Qingdao 266071, Peoples R China

关键词： Coordination polymer;Zinc;Luminescence;Crystal structure

期刊名称：JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS （ 影响因子：3.543； 五年影响因子：2.555 ）

ISSN： 1574-1443

年卷期： 2012 年 22 卷 4 期

页码：

收录情况： SCI

摘要： Two new coordination polymers [Zn(L)(bib)] (n) (1) and [Zn(L)(bib)(0.5)] (n) (2) [L = 5-hydroxyisophthalic acid and bib = 1,4-bis(2-methyl-imidazol-1-yl)butane] have been synthesized and characterized. X-ray single crystal diffractions show that complex 1 is a 2D layered structure and complex 2 is a 3D 6-connected topological net. Complex 1 are further assembled into a 3D supramolecular structure by intermolecular hydrogen bonding. Complex 2 features a two-fold interpenetrated pcu topology. Moreover, the fluorescent properties of complexes 1 and 2 were studied in the solid state at room temperature.

  • 相关文献

[1]Construction of cadmium(II) and zinc(II) coordination frameworks based on 3,5-bis(benzoimidazo-1-ly)pyridine and carboxylate acids: Synthesis, crystal structures and photoluminescent properties. Xu, Jiakun,Wang, Shuaiyu,Sun, Mi,Xu, Jiakun,Yan, Xingchen,Sun, Xiaochun,Yan, Xingchen. 2013

[2]Hydrothermal synthesis of five new coordination polymers based on benzophenone-2, 4'-dicarboxylic acid and N-donor spacers. Xu, Jiakun,Fan, Yuhua,Bi, Caifeng,Xu, Jiakun,Sun, Mi,Sun, Xiaochun.

[3]A New Ni(II) Coordination Polymer Constructed by the Dicarboxylate and Imidazole-Containing Ligand With Three-Fold Interpenetrating pcu Topological Net: Synthesis, Crystal Structure, and Luminescent Property. Xu, Jiakun,Ju, Caixia,Zhang, Quan,Sun, Mi,Xu, Jiakun,Sun, Xiaochun,Ju, Caixia,Zhang, Quan.

[4]Zinc coordination polymers with rigid dicarboxylates and semirigid 3,5-bis(imidazole-1-yl) pyridine: syntheses, structural topologies, and luminescent properties. Xu, Jiakun,Ju, Caixia,Sheng, Jun,Wang, Fang,Sun, Mi,Sun, Xiaochun,Ju, Caixia.

[5]Coordination Frameworks based on 3,5-Bis(imidazole-1-yl)pyridine and Aromatic Dicarboxylate Ligands: Synthesis, Crystal Structures, and Photoluminescent Properties. Xu, Jiakun,Sun, Mi,Xu, Jiakun,Yan, Xincheng,Bi, Caifeng,Sun, Xiaochun,Yang, Lirong.

[6]Crystal structures and theoretical calculations of two peculiar compounds derived from 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one. Yan, Xingchen,Wu, Xiaojing,Xu, Jiakun,Fan, Yuhua,Bi, Caifeng,Zhang, Xia,Zhang, Zhongyu,Yan, Xingchen,Xu, Jiakun. 2014

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