Effects of Hydrolysis Degree of Soy Protein Isolate On the Structure and Performance of Hydrolyzed Soy Protein Isolate/Urea/Formaldehyde Copolymer Resin
文献类型: 外文期刊
作者: Qu, Ping 1 ; Huang, Hongying 1 ; Wu, Guofeng 1 ; Sun, Enhui 1 ; Chang, Zhizhou 1 ;
作者机构: 1.Jiangsu Acad Agr Sci, Inst Agr Resources & Environm, Lab Agr Wastes Treatment & Recycling, Jiangsu Collaborat Innovat Ctr Solid Organ Waste, Nanjing 210014, Jiangsu, Peoples R China
关键词: adhesives;properties and characterization;thermal properties
期刊名称:JOURNAL OF APPLIED POLYMER SCIENCE ( 影响因子:3.125; 五年影响因子:2.754 )
ISSN: 0021-8995
年卷期: 2015 年 132 卷 7 期
页码:
收录情况: SCI
摘要: The hydrolyzed soy protein isolate (HSPI) with different hydrolysis degree was applied to modify urea-formaldehyde resins (UF) via copolymerization process. The properties of HSPI were characterized by attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) and TGA. The results show that HSPI with different hydrolysis degree is obtained. H-1 NMR and ATR-FTIR spectra indicate that HSPI with different hydrolysis degree can incorporate into the structure of cured and uncured UF. The UF modified with higher hydrolysis degree of HSPI possess more stable units and contribute to the lower exothermic peak temperature in DSC curves. The bonding strength of HSPI modified UF increases as the hydrolysis degree of HSPI increases at the hot-press temperature of 120 degrees C and decreases at the hot-press temperature of 150 degrees C. The best bonding strength is 1.53 MPa at the hot-press temperature of 135 degrees C and improved 56.12% compared with UF. In addition, the formaldehyde emission is dramatically reduced. (C) 2014 Wiley Periodicals, Inc.
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