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The behavior of natural rubber-epoxidized natural rubber-silica composites based on wet masterbatch technique

文献类型： 外文期刊

作者： Wang, Yueqiong 1 ; Liao, Lusheng 1 ; Zhong, Jieping 3 ; He, Dongning 1 ; Xu, Kui 1 ; Yang, Changjin 1 ; Luo, Yongyue 1 ;

作者机构： 1.Chinese Acad Trop Agr Sci, Agr Prod Proc Res Inst, Zhanjiang 524001, Peoples R China

2.Chinese Acad Trop Agr Sci, Rubber Res Inst, Danzhou 571737, Peoples R China

3.Guangdong Ocean Univ, Sch Sci, Zhanjiang 524088, Peoples R China

4.Univ So Queensland, Ctr Excellence Engn Fibre Composites, Toowoomba, Qld 4350, Australia

关键词： composites;mechanical properties;rubber

期刊名称：JOURNAL OF APPLIED POLYMER SCIENCE （ 影响因子：3.125； 五年影响因子：2.754 ）

ISSN： 0021-8995

年卷期： 2016 年 133 卷 26 期

页码：

收录情况： SCI

摘要： Natural rubber-epoxidized natural rubber-silica composites were prepared by the wet masterbatch technique and the traditional dry mixing method. Performances of the composites based on different preparation methods were investigated with a moving die rheometer, an electronic universal testing machine, a dynamic mechanical analyzer, a nuclear magnetic resonance crosslink density analyzer, a rubber processing analyzer (RPA), a scanning electron microscope (SEM), and a transmission electron microscope (TEM). The RPA, SEM, and TEM analyses indicated that silica has better dispersion, lower filler-filler interaction, and better filler-rubber interaction in compounds based on the wet masterbatch technique, leading to improvements in mechanical strength and the dynamic mechanical and compression properties of the composites. It also indicates that composites prepared by the wet masterbatch technique have shorter scorch time, faster curing velocity, and higher crosslink density. The composites prepared by the wet materbatch technique also have lower rolling resistance, which is an important property for their use as a green material for the tire industry. (c) 2016 Wiley Periodicals, Inc.

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