Electrochemical Selenylation-Induced Oxyselenation of Alkene Derivatives for the Synthesis of β-Hydroxyselenides
文献类型： 外文期刊
作者： Huang, Ruimin 1 ; Zhou, Ruichen 1 ; Hou, Jing 2 ; Hou, Guoan 1 ; Wan, Yaya 2 ; Zhou, Pengjuan 2 ; Tang, Dong 2 ;
作者机构： 1.Yinchuan Univ Energy, Sch Chem & Biol Engn, Yinchuan, Ningxia, Peoples R China
2.Ningxia Acad Agr & Forestry Sci, Inst Agr Resources & Environm, 590 Huanghe Rd, Yinchuan, Ningxia, Peoples R China
关键词： Diselenides; Electrosynthesis; Oxyselenation; Styrene; beta-Hydroxyselenides
期刊名称：CHEMISTRYSELECT （ 影响因子：2.0； 五年影响因子：2.0 ）
ISSN： 2365-6549
年卷期： 2025 年 10 卷 34 期
页码：
收录情况： SCI
摘要： We report an electrochemical method for the synthesis of beta-hydroxy selenides from functionalized alkenes and diselenides. This reaction uses tetrabutylammonium tetrafluoroborate (n-Bu4NBF4) as the electrolyte and acetonitrile (CH3CN) as the solvent for constant current electrolysis in an undivided electrolytic cell and provides moderate-to-good yields. The alkene derivatives, including carbamate and benzoate functionalized alkenes, are well tolerated. A plausible mechanism is proposed, and the reaction may involve the formation of selenium cation intermediates and the transition of six-membered ring intermediates.
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