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Preparation and applications of metal-organic frameworks in chiral chromatographic separation

文献类型： 外文期刊

作者： Gu, Zhida 4 ; Luo, Yongqi 2 ; Zhang, Xinglong 2 ; Zhu, Zhiyi 2 ; Wang, Yuchen 2 ; Tang, Tao 1 ; Zhang, Suoying 2 ; Zhang, Weina 2 ;

作者机构： 1.Zhejiang Acad Agr Sci, Inst Agroprod Safety & Nutr, Hangzhou 310021, Peoples R China

2.Nanjing Tech Univ NanjingTech, Sch Flexible Elect Future Technol, Key Lab Flexible Elect KLOFE, Nanjing 211816, Peoples R China

3.Nanjing Tech Univ NanjingTech, Inst Adv Mat IAM, Sch Flexible Elect Future Technol, Nanjing 211816, Peoples R China

4.Henan Univ, Sch Flexible Elect SoFE, Zhengzhou 450046, Peoples R China

5.Henan Univ, Henan Inst Flexible Elect HIFE, Zhengzhou 450046, Peoples R China

关键词： Metal-organic frameworks; Chiral stationary phase; Chiral chromatography; Enantiomeric separation

期刊名称：TRAC-TRENDS IN ANALYTICAL CHEMISTRY （ 影响因子：11.8； 五年影响因子：12.7 ）

ISSN： 0165-9936

年卷期： 2024 年 179 卷

页码：

收录情况： SCI

摘要： Separating pure enantiomers from racemates has long been a challenging and significant task across various scientific disciplines of biology, medicine, and chemistry. Over the past two decades, metal-organic frameworks (MOFs) have emerged as one of the most sought-after materials, showcasing unparalleled advantages in various applications. Chiral MOFs, in particular, have garnered increasing attention in enantiomeric separation. Unlike conventional materials, MOFs offer greater potential for achieving enantiomeric separation in chromatographic techniques due to their customizable chiral structures and adjustable pore environments. In this review, we aim to outline the remarkable progress and achievements of MOFs as stationary phases in the field of chromatographic enantiomeric separation including gas chromatography, high-performance liquid chromatography, and capillary electrochromatography. The discussions about MOF synthesis, column packing strategy, and MOFbased column performance, will improve our understanding about the design, immobilization, and separation mechanism for the MOF stationary phase. In addition, we explore the benefits, constraints, and future possibilities of these applications.

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