A novel approach for synthesizing α-amino acids via formate mediated hydrogen transfer using a carbon source
文献类型： 外文期刊
第一作者： Zhao, Tian-Tian
作者： Zhao, Tian-Tian;Zhang, Xu-Gang;He, Wen-Bo;Xu, Peng-Fei;Xu, Peng-Fei
作者机构：
期刊名称：GREEN CHEMISTRY （ 影响因子：9.8； 五年影响因子：9.8 ）
ISSN： 1463-9262
年卷期： 2023 年 25 卷 21 期
页码：
收录情况： SCI
摘要： Using a formate salt as a promising hydrogen carrier and one-carbon (C1) source, we have developed a novel and practical method for the preparation of alpha-amino acid derivatives under mild conditions. In this approach, the photoexcited naphthalene thiolate acts simultaneously as a photoexcited single-electron reductant and a hydrogen atom transfer (HAT) catalyst, enabling efficient metal-free radical-radical cross-coupling of formate with ketimines and aldimines.
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