Bio-based solvents for the Baylis-Hillman reaction of HMF

文献类型： 外文期刊

第一作者： Tan, Jia-Neng

作者： Tan, Jia-Neng;Ahmar, Mohammed;Queneau, Yves;Tan, Jia-Neng

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期刊名称：RSC ADVANCES （ 影响因子：3.361； 五年影响因子：3.39 ）

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收录情况： SCI

摘要： The Baylis-Hillman reaction of HMF was investigated in various bio-based solvent systems and in water. Although pure water is able to promote the reaction, aqueous mixtures with ethanol, isopropanol, methyl-THF (MeTHF), tetrahydrofurfuryl-alcohol (THFA) show better overall efficacy for the HMF Baylis-Hillman reaction than pure water or the pure bio-based solvent. Such solvent systems can replace THF or dioxane, often used for BH reactions. However, pure bio-based solvents can be used in the case of the more polar glucosyloxymethylfurfural (GMF). These results show that the most appropriate medium must also take into account the polarity of the starting aldehyde.

分类号： O6

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