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Development of fluorescent FeIII sensor based on chalcone

文献类型: 外文期刊

作者: Wei, Yanli 1 ; Qin, Guojie 2 ; Wang, Wenyan 1 ; Bian, Wei 1 ; Shuang, Shaomin 1 ; Dong, Chuan 1 ;

作者机构: 1.Shanxi Univ, Res Ctr Environm Sci & Engn, Taiyuan 030006, Peoples R China

2.Shanxi Acad Agr Sci, Inst Hort, Taiyuan 030031, Peoples R China

关键词: 4-Dimethylamino 2;5-dihydroxy chalcone;Fe~3 ion;Fluorescence quenching;Intramolecular charge transfer;Optochemical sensor

期刊名称:JOURNAL OF LUMINESCENCE ( 影响因子:3.599; 五年影响因子:3.006 )

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收录情况: SCI

摘要: In this paper, 4-dimethylamino 2,5-dihydroxy chalcone (DMADHC), which exhibits excited state intramolecular charge transfer (ICT) characteristics, was synthesized and characterized. A sensitive optochemical sensor for Fe ~3 ion was developed using DMADHC as fluorescence receptor. The fluorescence of DMADHC was gradually quenched with the addition of Fe ~3 ion, which attributed to the formation of 1:1 complex between DMADHC and Fe~3 ion. The sensor exhibited excellent selectivity for Fe~3 ion over a large number of cation ions such as alkali, alkaline earth and transitional metal ions with a linear range of 3.984×10 ~(-7)1.135×10~(-5) and a limit of detection of 8.223×10~(-8) mol/L. On this basis, the sensor was preliminary applied to the determination of the content of iron ions in multi-vitamin tablet with satisfied results and the recoveries were in the 95100% interval, and precision (n=5) was better than 5%.

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