A novel method for the simultaneous determination of esterified 2-/3-MCPD and glycidol in foods by GC-MS/MS
文献类型： 外文期刊
作者： Zheng, Xiaoling 1 ; Fu, Wusheng 1 ; Zheng, Kuicheng 1 ; Gao, Bo 2 ; Lin, Lishan 5 ; Liu, Wenjing 1 ; Lin, Zhong 1 ; Fang, 1 ;
作者机构： 1.Fujian Ctr Dis Control & Prevent, Fujian Prov Key Lab Zoonosis, Fuzhou 350001, Peoples R China
2.Fujian Entry Exit Inspect & Quarantine Bur, Fujian Int Travel Healthcare Ctr, Fuzhou 350001, Peoples R China
3.Fujian Med Univ, Affiliated Hosp 2, Dept Pharm, Quanzhou 362000, Peoples R China
4.Fujian Med Univ, Fuzhou 350108, Peoples R China
5.Fujian Agr & Forestry Univ, Sch Food Sci, Fuzhou 350002, Peoples R China
6.Fujian Univ Tradit Chinese Med, Sch Med, Fuzhou 350108, Peoples R China
7.Fujian Acad Agr Sci, Inst Biotechnol, Fuzhou 350003, Peoples R China
关键词： 3-Monochloro-1; 2-propanediol ester; 2-Monochloro-1; 3-propanediol ester; Glycidyl ester; Heptafluorobutyrylimidazole; GC-MS/MS
期刊名称：FOOD CONTROL （ 影响因子：5.548； 五年影响因子：5.498 ）
ISSN： 0956-7135
年卷期： 2021 年 123 卷
页码：
收录情况： SCI
摘要： Several critical improvements for simultaneous determination of 2- and 3-monochlompropanediol esters (2-MCPDE, 3-MCPDE) and glycidyl esters (GE) were established in this study. GE were converted into 3-monobromopropanediol monoesters (3-MBPDE) through bromination, then, 3-MBPDE, 2-MCPDE and 3-MCPDE were converted into their free forms through acid catalysis. The three target analytes were purified by matrix solid phase dispersion extraction and then derivatized with heptafluorobutyrylimidazole (HFBI). The derivatives were detected by GC-MS/MS, and key parameters including NaBr concentration, bromination time and temperature, and transesterification time were optimized. Finally the new procedure was fully validated. The limits of detection for 3-MCPDE, 2-MCPDE and GE in vegetable oil were 2.0, 5.0, and 10 mu g/kg, respectively. The average recoveries ranged from 85.4% to 110% with relative standard deviation ( RSD ) of 1.3%-7.4% when the spiked levels varied from 0.05 to 1.0 mg/kg. The trueness of the method was also successfully and consistently evaluated by the proficiency test in FAPAS.
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