Evaluation of cleanup procedures in pesticide multi-residue analysis with QuEChERS in cinnamon bark
文献类型： 外文期刊
作者： Zhang, Zihao 1 ; Dong, Maofeng 2 ; Hao, Xianghong 1 ; Han, Lijun 1 ; Song, Shuangyu 1 ; Yao, Wei 1 ;
作者机构： 1.China Agr Univ, Coll Sci, Beijing 100193, Peoples R China
2.Shanghai Acad Agr Sci, Pesticide Safety Evaluat Res Ctr, Inst Agrofood Stand & Testing Technol, Shanghai 201106, Peoples R China
关键词： QuEChERS; d-SPE; Repetitive d-SPE; Pesticides; Cinnamon
期刊名称：FOOD CHEMISTRY （ 影响因子：7.514； 五年影响因子：7.516 ）
ISSN： 0308-8146
年卷期： 2019 年 276 卷
页码：
收录情况： SCI
摘要： Cinnamon bark is a very complex spices matrix for pesticide residue analysis. In this study, two cleanup procedures, dispersive solid-phase extraction (d-SPE) and repetitive d-SPE, combined with Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) extraction were both investigated and applied for the determination of 60 pesticide residues in cinnamon bark by liquid chromatography - tandem mass spectrometry (LC-MS/MS) detection. The extraction solvents, phase partition salts, and cleanup sorbents were optimized. The results showed that 150 mg MgSO4 + 50 mg C-18 showed the best performance in d-SPE. The repetitive d-SPE achieved less matrix effects than d-SPE, but several high water-solubility analytes were lost during the cleanup, and also the 10 fold dilution compromised the sensitivities of analytes. With the validated QuEChERS-d-SPE method, 44 of 60 pesticides obtained satisfactory recoveries (71%-118%) and RSDs (2%-27%) at three to five spiking levels. The method was applied to monitor 15 market cinnamon samples.
- 相关文献
作者其他论文 更多>>
-
Development of a UPLC-MS/MS-based method for simultaneous determination of advanced glycation end products and heterocyclic amines in stewed meat products
作者：Wang, Tan;Zhao, Yueliang;Wang, Tan;Dong, Maofeng;Shen, Qinyi;Wen, Guangyue;Wang, Mingfu;Zhao, Yueliang;Wang, Mingfu
关键词：AGEs; HAs; UPLC-MS/MS; Stewed meat products
-
Development of Acid Hydrolysis-Based UPLC-MS/MS Method for Determination of Alternaria Toxins and Its Application in the Occurrence Assessment in Solanaceous Vegetables and Their Products
作者：Tang, Hongxia;Han, Wei;Fei, Shaoxiang;Li, Yubo;Huang, Jiaqing;Dong, Maofeng;Wang, Weimin;Dong, Maofeng;Wang, Lei;Zhang, Ying
关键词：Alternaria toxins; modified analytical method; solanaceous vegetables; solanaceous vegetable products; UPLC-MS; MS
-
Residue behaviors, degradation, processing factors, and risk assessment of pesticides in citrus from field to product processing
作者：Tang, Hongxia;Sun, Qiang;Huang, Jiaqing;Wen, Guangyue;Dong, Maofeng;Wang, Weimin;Han, Lijun;Wang, Lei;Zhang, Ying
关键词：Citrus; Processing factors; Dissipation; Residue levels; Risk assessment
-
Fluorescent labeling and tracing of immobilized efficient degrading bacterium DNB-S1 and its remediation efficiency of DBP contaminated soil
作者：Wang, Lei;Jia, Xiaochen;Dou, Zeyu;Li, Xiaoqian;Bao, Wenjing;Ma, Chaoran;Wang, Hongye;Zhang, Ying;Dong, Maofeng
关键词：GFP fluorescence Labeling; DBP; Immobilized bacteria; Biodegradation; Dynamics
-
Oxic effects of Pb-Ce compound pollution on Chinese cabbage and programmed cell death in root tip cells
作者：Wang, Lei;Ma, Chaoran;Jia, Xiaochen;Dou, Zeyu;Wang, Hongye;Bao, Wenjing;Qu, Jianhua;Zhang, Ying;Dong, Maofeng
关键词：Ce; Pb; Compound pollution; Programmed cell death; Toxic effects
-
Optimization and validation of an oxidation and solid-phase extraction procedure for analysis of imidacloprid and its metabolites in cereals using ultra-performance liquid chromatography tandem mass spectrometry
作者：Wang, Tan;Sun, Qiang;Wang, Weimin;Dong, Maofeng;Wang, Tan;Zhao, Yueliang;Zhang, Songhan;Ma, Lin;Zhao, Li;Dong, Maofeng
关键词：Imidacloprid; 6-Chloronicotinic acid; Oxidation; UPLC-MS/MS; Cereals
-
Effect of acrolein on the formation of harman and norharman in chemical models and roast beef patties
作者：Wang, Yuanyuan;Zhu, Yamin;Jiang, Qingqing;Zhao, Yueliang;Dong, Maofeng;Guo, Limin;Xiao, Jianbo;Wang, Mingfu;Zhao, Yueliang
关键词：Harman; Norharman; Acrolein; Intermediates; Elimination
