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Recent Developments in the Synthesis of Nitrogen-Containing Heterocycles through C-H/N-H Bond Functionalizations and Oxidative Cyclization

文献类型： 外文期刊

作者： Liu, Xiang 1 ; Huang, Yu 1 ; Meng, Xu 2 ; Li, Jihui 3 ; Wang, Dong 4 ; Chen, Yongxin 5 ; Tang, Dong 7 ; Chen, Baohua 8 ;

作者机构： 1.China Three Gorges Univ, Coll Mat & Chem Engn, Key Lab Inorgan Nonmetall Crystalline & Energy Co, Yichang 443002, Hubei, Peoples R China

2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Suzhou Res Inst, Lanzhou 730000, Gansu, Peoples R China

3.Hainan Univ, Coll Mat & Chem Engn, Haikou 570228, Hainan, Peoples R China

4.Shenzhen Univ, Ctr AIE Res, Coll Mat Sci & Engn, Shenzhen 518060, Peoples R China

5.Chinese Acad Sci, Key Lab Petr Resources, Inst Geol & Geophys, Lanzhou 730000, Gansu, Peoples R China

6.Chinese Acad Sci, Key Lab Petr Resources Res, Inst Geol & Geophys, Lanzhou 730000, Gansu, Peoples R China

7.Ningxia Acad Agr & Forestry Sci, Yinchuan 750002, Peoples R China

8.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China

关键词： oxidative cyclization; C-H bond activation; nitrogen heterocycles; N-H bond activation

期刊名称：SYNLETT （ 影响因子：2.454； 五年影响因子：2.136 ）

ISSN： 0936-5214

年卷期： 2019 年 30 卷 9 期

页码：

收录情况： SCI

摘要： The synthesis and structure of nitrogen-containing heterocycles are fascinating because these compounds have a great richness of structural, physicochemical, and biological properties. Therefore, the development of improved ways for the synthesis of polyfunctional nitrogen-containing heterocycles continues to be a challenging goal. This account describes developments in the discovery of C-H/N-H bond functionalization and oxidative cyclization procedures for the synthesis of nitrogen-containing heterocycles (aziridines, indoles, indolizines, triazoles, imidazoles, oxazoles, thiazoles, quinoxalines, triazines, and pyridines) in our laboratories during the last 15 years. 1 Introduction 2 Synthesis of Aziridines 3 Synthesis of Indoles and Indolizines 4 Synthesis of Triazoles 5 Synthesis of Imidazoles 6 Synthesis of Oxazoles and Thiazoles 7 Synthesis of Quinoxalines, Triazines, and Pyridines 8 Conclusion and Outlook

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