Electrochemical Selenylation-Induced Oxyselenation of Alkene Derivatives for the Synthesis of β-Hydroxyselenides
文献类型： 外文期刊
作者： Huang, Ruimin 1 ; Zhou, Ruichen 1 ; Hou, Jing 2 ; Hou, Guoan 1 ; Wan, Yaya 2 ; Zhou, Pengjuan 2 ; Tang, Dong 2 ;
作者机构： 1.Yinchuan Univ Energy, Sch Chem & Biol Engn, Yinchuan, Ningxia, Peoples R China
2.Ningxia Acad Agr & Forestry Sci, Inst Agr Resources & Environm, 590 Huanghe Rd, Yinchuan, Ningxia, Peoples R China
关键词： Diselenides; Electrosynthesis; Oxyselenation; Styrene; beta-Hydroxyselenides
期刊名称：CHEMISTRYSELECT （ 影响因子：2.0； 五年影响因子：2.0 ）
ISSN： 2365-6549
年卷期： 2025 年 10 卷 34 期
页码：
收录情况： SCI
摘要： We report an electrochemical method for the synthesis of beta-hydroxy selenides from functionalized alkenes and diselenides. This reaction uses tetrabutylammonium tetrafluoroborate (n-Bu4NBF4) as the electrolyte and acetonitrile (CH3CN) as the solvent for constant current electrolysis in an undivided electrolytic cell and provides moderate-to-good yields. The alkene derivatives, including carbamate and benzoate functionalized alkenes, are well tolerated. A plausible mechanism is proposed, and the reaction may involve the formation of selenium cation intermediates and the transition of six-membered ring intermediates.
- 相关文献
作者其他论文 更多>>
-
Ruthenium-catalyzed reaction of dinitriles with primary alcohols for the synthesis of N-alkylated cyclic β-enaminonitriles
作者：Ma, Wei;Zhao, Qiang;Su, Shibin;Zhang, Weiwei;Yao, Yao;Wang, Pei;Tang, Dong;Zhou, Pengjuan
关键词：N-alkylated cyclic beta-enaminonitriles; aliphatic dinitrile; primary alcohol; ruthenium-catalyzed
-
Base-Catalyzed Cascade Cyclization of Acyl Cyanides and Isocyanates for the Synthesis of Oxazoles
作者：Zhang, Wei;Li, Hongjun;Hou, Jing;Wan, Yaya;Zhou, Pengjuan;Tang, Dong
关键词：Acyl cyanides; Base-promoted; Cyclization reaction; Oxazoles; Isocyanates
-
Synergism between Surface Engineering and S-Scheme Heterojunctions for Efficient Photocatalytic H2 Evolution
作者：Guo, Xin;Wen, Bo;Liu, Jiayue;Jin, Zhiliang;Tang, Dong;Li, Youji
关键词：
-
Selected Electrosynthesis of 3-Aminopyrazoles from α,β-Alkynic Hydrazones and Secondary Amines
作者：Tang, Dong;Zhang, Wei;Ji, Jingwen;Jiang, Rui;Wan, Yaya;Zhou, Pengjuan;Ma, Wei
关键词：
-
Synthesis of N1-caffeoyl-N10-dihydrocaffeoylspermidine (Scotanamine D)
作者：Ji, Jingwen;Iqbal, Zafar;Sun, Jian;Zhou, Pengjuan;Zhai, Lijuan;He, Lili;Tang, Dong;Ji, Jinbo;Yang, Haikang;Yang, Zhixiang;Li, Liuyan
关键词：N1-caffeoyl-N10-dihydrocaffeoylspermidine; spermidine; alkaloid; yields; medicinally valuable; natural compound; synthesis
-
Convenient Synthesis of Bis-(Dihydro)Caffeoylspermine
作者：Zhai, Lijuan;Sun, Jian;Zhou, Pengjuan;Ji, Jingwen;He, Lili;Tang, Dong;Ji, Jinbo;Yang, Haikang;Iqbal, Zafar;Yang, Zhixiang
关键词：kukoamine A; natural product; dihydrocaffeic acid; spermine
-
Electrochemical Selenylation-Induced Annulation of Alkenyl Ureas to Access Cyclic Isoureas
作者：Li, Hongjun;Yang, Jinhui;Tang, Dong;Zhou, Pengjuan;Wan, Yaya;Jiang, Rui
关键词：Alkenyl ureas; Selenylation; Electrochemistry; Cyclic isoureas; C-O/C-Se bond formation
