Sulfate-accelerated photochemical oxidation of arsenopyrite in acidic systems under oxic conditions: Formation and function of schwertmannite
文献类型： 外文期刊
作者： Hong, Jun 1 ; Liu, Lihu 2 ; Zhang, Ziwei 2 ; Xia, Xiange 1 ; Yang, Li 1 ; Ning, Zengping 3 ; Liu, Chengshuai 3 ; Qiu, Guohong 2 ;
作者机构： 1.Hubei Acad Agr Sci, Inst Plant Protect & Soil Fertilizer, Key Lab Fertilizat Agr Wastes, Minist Agr & Rural Affairs, Wuhan 430070, Hubei, Peoples R China
2.Huazhong Agr Univ, Interdisciplinary Sci Inst, Coll Resources & Environm, Wuhan 430070, Hubei, Peoples R China
3.Chinese Acad Sci, Inst Geochem, State Key Lab Environm Geochem, Guiyang 550081, Guizhou, Peoples R China
关键词： Arsenopyrite; Photochemical oxidation; Acid mine drainage; Sulfate; Schwertmannite
期刊名称：JOURNAL OF HAZARDOUS MATERIALS （ 影响因子：14.224； 五年影响因子：12.984 ）
ISSN： 0304-3894
年卷期： 2022 年 433 卷
页码：
收录情况： SCI
摘要： The weathering of arsenopyrite is closely related to the generation of acid mine drainage (AMD) and arsenic (As) pollution. Solar radiation can accelerate arsenopyrite oxidation, but little is known about the further effect of SO42- on the photochemical process. Here, the photooxidation of arsenopyrite was investigated in the presence of SO42- in simulated AMD environments, and the effects of SO42- concentration, pH and dissolved oxygen on arsenopyrite oxidation were studied as well. SO42- could accelerate the photooxidation of arsenopyrite and As (III) through complexation between nascent schwertmannite and As(III). Fe(II) released from arsenopyrite was oxidized to form schwertmannite in the presence of SO42-, and the photooxidation of arsenopyrite occurred through the ligand-to-metal charge-transfer process in schwertmannite-As(III) complex along with the formation of reactive oxygen species in the presence of O2. The photooxidation rate of arsenopyrite first rose and then fell with increasing SO42- concentration. In the pH range of 2.0-4.0, the photooxidation rate of arsenopyrite progressively increased in the presence of SO42- . This study reveals how SO42- promotes the photooxidation of arsenopyrite and As release in the AMD environment, and improves the understanding of the transformation and migration of As in mining areas.
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