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The Development of Ionic Liquids as Stationary Phases for Gas Chromatography

文献类型： 外文期刊

作者： Sun Xiaojie 1 ; Xing Jun 4 ; Zhai Yuxiu 1 ; Li Zhaoxin 1 ;

作者机构： 1.Chinese Acad Fishery Sci, Key Lab Testing & Evaluat Aquat Prod Safety & Qua, Minist Agr, Qingdao 266071, Peoples R China

2.Chinese Acad Fishery Sci, Yellow Sea Fisheries Res Inst, Qingdao 266071, Peoples R China

3.Natl Ctr Qual Supervis & Test Aquat Prod, Qingdao 266071, Peoples R China

4.Wuhan Univ, Coll Chem & Mol Sci, Minist Educ, Key Lab Analyt Chem Biol & Med, Wuhan 430072, Peoples R China

关键词： gas chromatography;stationary phases;ionic liquid

期刊名称：PROGRESS IN CHEMISTRY （ 影响因子：1.172； 五年影响因子：0.929 ）

ISSN： 1005-281X

年卷期： 2014 年 26 卷 4 期

页码：

收录情况： SCI

摘要： In this paper, the development of ionic liquids as stationary phases for gas chromatography is briefly described. In order to improve the thermal stability, selectivity and column efficiency of ionic liquid stationary phases, the synthesis methods of ionic liquid stationary phases with achiral selectivity are developed successively, including small molecule ionic liquids, bulky ionic liquids, polymeric ionic liquids, physical mixed ionic liquids and chemically bonded ionic liquids. Meanwhile, ionic liquids are applied in chiral gas chromatography, employed as the solvent of chiral selectors or as chiral stationary phases of gas chromatography. Chiral pools of these ionic liquids are mostly from amino acids, chiral amines and bonded cyclodextrins. The differences in selectivity of these ionic liquid stationary phases are also discussed and reviewed. Then, the application of ionic liquids in two-dimensional gas chromatography and fast gas chromatography are introduced. Finally, the synthesis and application of ionic liquids in gas chromatography are summarized. The prospects of ionic liquid as novel separation materials are also discussed and forecasted.

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