Vapor deposition polymerization of aniline on 3D hierarchical porous carbon with enhanced cycling stability as supercapacitor electrode
文献类型： 外文期刊
作者： Zhao, Yufeng 1 ; Zhang, Zhi 1 ; Ren, Yuqin 2 ; Ran, Wei 1 ; Chen, Xinqi 3 ; Wu, Jinsong 3 ; Gao, Faming 1 ;
作者机构： 1.Yanshan Univ, Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China
2.Chinese Acad Fishery Sci, Beidaihe Ctr Expt Stn, Beidaihe 066100, Peoples R China
3.Northwestern Univ, NUANCE Ctr, EPIC, Evanston, IL 60208 USA
关键词： Hierarchical porous;Composite;Supercapacitor;Electrochemical performance
期刊名称：JOURNAL OF POWER SOURCES （ 影响因子：9.127； 五年影响因子：8.096 ）
ISSN： 0378-7753
年卷期： 2015 年 286 卷
页码：
收录情况： SCI
摘要： In this work, a polyaniline coated hierarchical porous carbon (HPC) composite (PANI@HPC) is developed using a vapor deposition polymerization technique. The as synthesized composite is applied as the supercapacitor electrode material, and presents a high specific capacitance of 531 F g(-1) at current density of 0.5 A g(-1) and superior cycling stability of 96.1% (after 10,000 charge discharge cycles at current density of 10 A g(-1)). This can be attributed to the maximized synergistic effect of PANI and HPC. Furthermore, an aqueous symmetric supercapacitor device based on PANI@HPC is fabricated, demonstrating a high specific energy of 17.3 Wh kg(-1). (C) 2015 Elsevier B.V. All rights reserved.
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