Electrochemical Cyclization of α,β-Alkynic Hydrazones and Primary Amines for the Synthesis of 3-Alkynyltriazoles
文献类型： 外文期刊
作者： Zhou, Pengjuan 1 ; Li, Hongjun 2 ; Jiang, Rui 1 ; Wan, Yaya 1 ; Hou, Jing 1 ; Hong, Yu 1 ; Tang, Dong 1 ;
作者机构： 1.Ningxia Acad Agr & Forestry Sci, Ningxia Ctr Agr Organ Synth, Agr Resource & Environm Inst, 590 Huanghe Rd, Yinchuan, Ningxia, Peoples R China
2.Ningxia Univ, Coll Chem & Chem Engn, State Key Lab High Efficiency Utilizat Coal & Gree, Yinchuan 750021, Peoples R China
关键词： alpha,beta-Alkynic hydrazones; Primary amines; 3-Alkynyltriazoles; Electrosynthesis; Iodine-mediated
期刊名称：ASIAN JOURNAL OF ORGANIC CHEMISTRY （ 影响因子：2.7； 五年影响因子：2.6 ）
ISSN： 2193-5807
年卷期： 2023 年
页码：
收录情况： SCI
摘要： An environmentally friendly iodine-catalyzed electrochemical synthetic protocol has developed to access 3-alkynyltriazoles through the cyclization of alpha,beta-alkynic hydrazones and primary amines. This reaction is carried out without the addition of electrolyte with excellent functional group tolerance in an undivided cell under mild conditions, affording substituted 3-alkynyltriazoles with moderate to good yields. The gram scale reaction demonstrates the potential of this protocol in industrial synthesis.
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