文献类型： 外文期刊

作者： Pan, Yating ¹ ; Yang, Xue ² ; Wei, Haijuan ³ ; Liu, Xiang ¹ ; Wang, Pan ² ; Duan, Nina ² ; Lin, Miao ⁴ ;

作者机构： 1.Fudan Univ, Dept Environm Sci & Engn, Shanghai 200438, Peoples R China

2.Shanghai Municipal Engn Design Inst Grp Co Ltd, Shanghai 200092, Peoples R China

3.Shanghai Chengtou Wastewater Treatment Co Ltd, Shanghai 201203, Peoples R China

4.Shanghai Acad Agr Sci, Shanghai 201403, Peoples R China

关键词： biogas residue; biochar; wastewater; peroxymonosulfate; advanced oxidation process; catalyst regeneration

期刊名称：WATER （ 影响因子：3.0； 五年影响因子：3.3 ）

ISSN：

年卷期： 2025 年 17 卷 5 期

页码：

收录情况： SCI

摘要： The biogas residue (BR) from the anaerobic digestion of sludge poses a threat to the environment due to the presence of toxic and hazardous substances. Furthermore, emerging contaminants, such as bisphenol A (BPA), are widespread in domestic and industrial wastewater, requiring efficient and sustainable treatment technologies. In this study, the BR-based biochar was pyrolyzed from urea-modified BR and employed as a catalyst to activate peroxymonosulfate (PMS) for BPA degradation. With BR-based biochar pyrolyzed at 750 degrees C as a catalyst, 20 mg/L of BPA was completely removed. Free radical detection confirmed that hydroxyl radical (center dot OH) and sulfate radical (center dot SO4-) generation decreased with the increase in catalyst reuse times. The X-ray photoelectron spectra showed that the catalyst deactivation mainly resulted from -COOH and C-OH group loss, which acted as active sites for generating center dot OH and center dot SO4-, and HCl or NaOH regeneration for catalysts could recover oxygen-containing functional groups, boosting BPA removal from 54.7% to 91.5% and 100%, respectively. Thermal regeneration could only enlarge the catalyst's specific surface area (SSA) to recover adsorption capacity, but might not restore the free radical generation capability. This research offered a theoretical basis for the sustainable utilization of BR and provided a reference for reusing catalysts in wastewater treatment.