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New 2-(2-Phenylethyl)chromone derivatives from agarwood originating from Aquilaria sinensis

文献类型： 外文期刊

作者： Li, Jun-Tao 1 ; Kuang, Tong-Dong 1 ; Chen, Hui-Qin 1 ; Yang, Li 1 ; Wang, Hao 1 ; Cai, Cai-Hong 1 ; Liu, Shou-Bai 2 ; Mei, Wen-Li 1 ; Dai, Hao-Fu 1 ;

作者机构： 1.Chinese Acad Trop Agr Sci, Inst Trop Biosci & Biotechnol, Hainan Inst Trop Agr Resources, Hainan Key Lab Res & Dev Nat Prod Li Folk Med, Haikou 571101, Hainan, Peoples R China

2.Hainan Univ, Coll Forestry,Minist Educ, Hainan Key Lab Biol Trop Specif Ornamental Plants, Key Lab Genet & Germplasm Enhancement Trop Specif, Haikou 570228, Hainan, Peoples R China

关键词： Agarwood; Aquilaria sinensis; 2-(2-phenylethyl)chromone; ECD calculation

期刊名称：JOURNAL OF ASIAN NATURAL PRODUCTS RESEARCH （ 影响因子：1.61； 五年影响因子：1.591 ）

ISSN： 1028-6020

年卷期：

页码：

收录情况： SCI

摘要： Two new dimeric 2-(2-phenylethyl)chromones, aquilasinenones L and M (1 and 2), and one new monomer analogue, 5S, 6 R, 7S, 8 R-tetrahydroxy-[2-(3-methoxy-4-hydroxyphenyl)ethyl]- 5,6,7,8-tetrahydrochromone (3), together with two known compounds, were isolated from the artificial agarwood originating from Aquilaria sinensis. Compound 1 was the first structure found with C8-O-C4"' linkage among 2-(2-phenylethyl)chromone dimers. Their structures were unambiguously elucidated based on 1 D and 2 D NMR spectroscopy, as well as by comparison with the literature. The absolute configuration was determined by ECD calculation. None of the compounds exhibited acetylcholinesterase inhibitory activity.

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