文献类型： 外文期刊
作者： Chen, Mengxin 1 ; Song, Chuqiao 3 ; Liang, Ce 2 ; Zhang, Bin 2 ; Sun, Yanchun 1 ; Li, Siwei 4 ; Lin, Lili 3 ; Xu, Ping 2 ;
作者机构： 1.Minist Agr & Rural Areas, Chinese Acad Fishery Sci, Heilongjiang River Fisheries Res Inst, Lab Qual & Safety Risk Assessment Aquat Prod, Harbin 150070, Peoples R China
2.Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Peoples R China
3.Zhejiang Univ Technol, Coll Chem Engn, Inst Ind Catalysis, State Key Lab Green Chem Synth Technol, Hangzhou 310014, Zhejiang, Peoples R China
4.Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Inst Ind Catalysis, Xian 710049, Peoples R China
期刊名称：INORGANIC CHEMISTRY FRONTIERS （ 影响因子：7.779； 五年影响因子：7.154 ）
ISSN： 2052-1553
年卷期： 2022 年 9 卷 11 期
页码：
收录情况： SCI
摘要： Here we demonstrate crystalline phase induced Raman enhancement on molybdenum carbide materials (beta-Mo2C and alpha-MoC). From all the studied target molecules (rhodamine 6G, crystal violet and methylene blue), the Raman enhancement on beta-Mo2C is 2-4 times higher than that on alpha-MoC. Spectroscopic and theoretical calculations reveal that beta-Mo2C has a lower electron work function and a higher density of states near the Fermi level than alpha-MoC, which promotes the charge transfer and photo induced charge transfer processes from probe molecules to the substrate.
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