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Interference between di(2-ethylhexyl) phthalate and heavy metals (Cd and Cu) in a Mollisol during aging and mobilization

文献类型： 外文期刊

作者： Huang, Fuxin 1 ; Guan, Rui 1 ; Wang, Jingyi 1 ; Wang, Lei 1 ; Zhang, Ying 1 ; Wang, Shiyu 2 ; Qu, Jianhua 1 ; Dong, Maofeng 3 ; Rong, Shaowen 1 ;

作者机构： 1.Northeast Agr Univ, Sch Resources & Environm, Harbin 150030, Peoples R China

2.Chinese Acad Agr Sci, Inst Agr Resources & Reg Planning, Minist Agr Key Lab Plant Nutr & Fertilizer, Beijing 100081, Peoples R China

3.Shanghai Acad Agr Sci, Pesticide Safety Evaluat Res Ctr, Shanghai 201106, Peoples R China

关键词： Phthalates; Heavy metals; Combined pollution; Pollutant aging; Leaching; Molecular dynamics simulation

期刊名称：SCIENCE OF THE TOTAL ENVIRONMENT （ 影响因子：10.753； 五年影响因子：10.237 ）

ISSN： 0048-9697

年卷期： 2022 年 836 卷

页码：

收录情况： SCI

摘要： Diffuse pollution of the soil by phthalates and heavy metals causes numerous concerns. Their respective fates when coexisting require further investigation. In this study, di(2-ethylhexyl) phthalate (DEHP) and Cd/Cu were used as subjects, focusing on their behavior in Mollisols under combined pollution based on their concentration, fractionation, and leaching. The results indicated that when the two pollutants coexist, the dissipation rate of DEHP in the soil decreased, and its half-life was extended from 30.81 to 40.53 (Cd) and 35.40 d (Cu). DEHP altered the distribution of Cd and Cu in the soil, and this effect persisted after most of the DEHP had degraded. Leaching tests showed that the interaction of DEHP with Cd and Cu hindered leaching during the first rainfall event, but as DEHP degraded and Cd/Cu stabilized, the trapped pollutants were gradually released in subsequent rainfall events. Additionally, to investigate the partitioning of pollutants between soil water and solid surfaces, a diffusion model of DEHP and metal ions on the surface of montmorillonite (high specific surface area adsorbents abundant in soils) was built using molecular dynamics simulations. Simulations revealed their density distribution on the clay surface increased synergistically, whereas their diffusion was antagonistic. This study provides basic data and theoretical support concerning the ecological risk assessment of combined phthalate and heavy metals pollution in soil.

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[1]Interference between di(2-ethylhexyl) phthalate and heavy metals (Cd and Cu) in a Mollisol during aging and mobilization. Huang, Fuxin,Guan, Rui,Wang, Jingyi,Wang, Lei,Zhang, Ying,Qu, Jianhua,Rong, Shaowen,Wang, Shiyu,Dong, Maofeng. 2022

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