文献类型： 外文期刊

作者： Liao Tao ¹ ; Wu Xiao-Cui ¹ ; Wang Shao-Hua ¹ ; Xie Song-Guang; Xiong Guang-Quan ¹ ; Geng Sheng-Rong ¹ ; Li Xin ¹ ; Zu ¹ ;

作者机构： 1.Hubei Acad Agr Sci, Inst Farm Prod Proc & Nucl Agr Technol, Hubei Engn Res Ctr Farm Prod Irradiat, Wuhan 430064, Peoples R China

2.Huazhong Agr Univ, Coll Food Sci & Technol, Wuhan 430070, Peoples R China

3.Huazhong Agr Univ, Coll Food Sci & Tech

关键词： River water estrogens;Solid phase extraction;Gas chromatography-mass spectrometry

期刊名称：CHINESE JOURNAL OF ANALYTICAL CHEMISTRY （ 影响因子：1.134； 五年影响因子：0.909 ）

ISSN： 0253-3820

年卷期： 2013 年 41 卷 3 期

页码：

收录情况： SCI

摘要： Nine target compounds including estrone (E-1), 17 beta-estradiol (17 beta-E-2), estriol (E-3) 4-octylphenol(4-OP), 4-nonylphenol (4-NP), bisphenol A (BPA), diethylstilbestrol (DES), mestranol (EE3ME) and 17 alpha-ethinyl estradiol (17 alpha-EE2) were simultaneous detected by SPE-GC-MS. Extraction and derivatization conditions were optimized. The results showed that the average recoveries of the nine target estrogens extracted by Oasis HLB cartridges were higher than those by Satara cartridges, the optimal temperature of derivatization reaction was 75 degrees C and the optimal time of derivatization reaction was 90 min. The average recoveries of the nine target estrogens by Oasis HLB cartridges were 60.5% - 126.7%, and the relative standard deviations (RSD) were 0.8% - 11.1%, and the limits of detection (LOD) ranged from 1.08 ng/L to 8.60 ng/L. This method has been employed to detect the estrogens in environment samples from rivers.