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Ultra-Highly Stiff and Tough Shape Memory Polyurea with Unprecedented Energy Density by Precise Slight Cross-Linking

文献类型： 外文期刊

作者： Chen, Jiaoyang 1 ; Wang, Zhifeng 2 ; Yao, Bowen 1 ; Geng, Yuhao 1 ; Wang, Cheng 3 ; Xu, Jianhua 1 ; Chen, Tao 1 ; Jing, Jiajie 1 ; Fu, Jiajun 1 ;

作者机构： 1.Nanjing Univ Sci & Technol, Sch Chem & Chem Engn, Nanjing 210094, Peoples R China

2.Yangzhou Univ, Testing Ctr, Yangzhou 225002, Peoples R China

3.Jiangsu Acad Agr Sci, Inst Agr Prod Proc, Nanjing 210014, Peoples R China

关键词： covalent and supramolecular bonds; environmental stability and recyclability; high energy density; mechanical robustness and toughness; shape memory polymers

期刊名称：ADVANCED MATERIALS （ 影响因子：29.4； 五年影响因子：30.2 ）

ISSN： 0935-9648

年卷期： 2024 年

页码：

收录情况： SCI

摘要： Shape memory polymers (SMPs) have attracted significant attention and hold vast potential for diverse applications. Nevertheless, conventional SMPs suffer from notable shortcomings in terms of mechanical properties, environmental stability, and energy density, significantly constraining their practical utility. Here, inspired by the structure of muscle fibers, an innovative approach that involves the precise incorporation of subtle, permanent cross-linking within a hierarchical hydrogen bonding supramolecular network is reported. This novel strategy has culminated in the development of covalent and supramolecular shape memory polyurea, which exhibits exceptional mechanical properties, including high stiffness (1347 MPa), strength (82.4 MPa), and toughness (312.7 MJ m-3), ensuring its suitability for a wide range of applications. Furthermore, it boasts remarkable recyclability and repairability, along with excellent resistance to moisture, heat, and solvents. Moreover, the polymer demonstrates outstanding shape memory effects characterized by a high energy density (24.5 MJ m-3), facilitated by the formation of strain-induced oriented nanostructures that can store substantial amounts of entropic energy. Simultaneously, it maintains a remarkable 96% shape fixity and 99% shape recovery. This delicate interplay of covalent and supramolecular bonds opens up a promising pathway to the creation of high-performance SMPs, expanding their applicability across various domains. An innovative approach utilizing a delicate balance of precise covalent bonds and hierarchical supramolecular interactions has resulted in an advanced shape memory polymer. This polymer boasts a unique combination of high stiffness, strength, and toughness, coupled with excellent resistance to humidity and heat, repairability, high energy density, and exceptional energy output, which allows for a wide range of potential applications. image

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