Ru-Catalyzed O-H Insertion of Sulfoxonium Ylide and Carboxylic Acid to Synthesize alpha-Acyloxy Ketones
文献类型： 外文期刊
作者： Mu, Yangxiu 1 ; Chen, Yongxin 2 ; Gao, Yuanyu 1 ; Sun, Jian 1 ; Iqbal, Zafar 1 ; Wan, Yaya 1 ; Yang, Minghua 3 ; Yang, Zh 1 ;
作者机构： 1.Ningxia Acad Agr & Forestry Sci, Inst Ningxia Ctr Agr Organ Synth, Agr Resource & Environm Inst, Yinchuan 750002, Ningxia, Peoples R China
2.Chinese Acad Sci, Northwest Inst Ecoenvironm & Resources, Lanzhou, Peoples R China
3.Lishui Univ, Dept Chem, Lishui, Peoples R China
关键词： alpha-Acyloxy ketones; Carboxylic acid; Excellent selectivity; O-H insertion; Sulfoxonium ylide
期刊名称：CHEMISTRYSELECT （ 影响因子：2.109； 五年影响因子：2.054 ）
ISSN： 2365-6549
年卷期： 2020 年 5 卷 5 期
页码：
收录情况： SCI
摘要： A Ru-catalyzed method is developed for the synthesis of alpha-acyloxy ketones from sulfoxonium ylide and carboxylic acid. The strategy achieves an excellent selectivity in the presence of 1,10-phenanthroline as ligand to afford the corresponding product in good yields under simple conditions. The reaction is believed to provide an alternative method to generate ester compounds.
- 相关文献
作者其他论文 更多>>
-
Selected Electrosynthesis of 3-Aminopyrazoles from α,β-Alkynic Hydrazones and Secondary Amines
作者：Tang, Dong;Zhang, Wei;Ji, Jingwen;Jiang, Rui;Wan, Yaya;Zhou, Pengjuan;Ma, Wei
关键词：
-
Synthesis of N1-caffeoyl-N10-dihydrocaffeoylspermidine (Scotanamine D)
作者：Ji, Jingwen;Iqbal, Zafar;Sun, Jian;Zhou, Pengjuan;Zhai, Lijuan;He, Lili;Tang, Dong;Ji, Jinbo;Yang, Haikang;Yang, Zhixiang;Li, Liuyan
关键词：N1-caffeoyl-N10-dihydrocaffeoylspermidine; spermidine; alkaloid; yields; medicinally valuable; natural compound; synthesis
-
Convenient Synthesis of Bis-(Dihydro)Caffeoylspermine
作者：Zhai, Lijuan;Sun, Jian;Zhou, Pengjuan;Ji, Jingwen;He, Lili;Tang, Dong;Ji, Jinbo;Yang, Haikang;Iqbal, Zafar;Yang, Zhixiang
关键词：kukoamine A; natural product; dihydrocaffeic acid; spermine
-
Electrochemical Selenylation-Induced Annulation of Alkenyl Ureas to Access Cyclic Isoureas
作者：Li, Hongjun;Yang, Jinhui;Tang, Dong;Zhou, Pengjuan;Wan, Yaya;Jiang, Rui
关键词：Alkenyl ureas; Selenylation; Electrochemistry; Cyclic isoureas; C-O/C-Se bond formation
-
A Convenient Synthesis of Bis-(dihydro)caffeoylspermidines
作者：He, Lili;Sun, Jian;Zhou, Pengjuan;Ji, Jingwen;Zhai, Lijuan;Tang, Dong;Ji, Jinbo;Yang, Haikang;Iqbal, Zafar;Yang, Zhixiang
关键词：Spermidine; caffeoylspermidine; dihydrocaffeoylspermidine; spermidine alkaloids; convenient synthesis; high yield
-
An efficient and environment-friendly halogenation of imidazoheterocycles with Bu 4 NX (X = Cl, Br and I) using iodobenzene diacetate as oxidant
作者：Yang, Minghua;Shao, Yating;Tang, Dong;Zhang, Wei;Wan, Yaya;Zhou, Pengjuan;Tang, Dong
关键词：Imidazoheterocycles; Iodobenzen diacetate; Halogenation; Tetrabutylammonium halide; 3-Haloimidazopyridine
-
Improved synthesis and evaluation of preclinical pharmacodynamic parameters of a new monocyclic β-lactam DPI-2016
作者：Zhai, Lijuan;Sun, Jian;Ji, Jingwen;He, Lili;Zhou, Pengjuan;Tang, Dong;Ji, Jinbo;Yang, Haikang;Iqbal, Zafar;Yang, Zhixiang
关键词：Monobactam; Aztreonam; beta-lactams; Antibacterial
