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Anionic oxygen vacancies in Nb2O5-x/carbon hybrid host endow rapid catalytic behaviors for high-performance high areal loading lithium sulfur pouch cell

文献类型： 外文期刊

作者： Cheng, Shuang 1 ; Wang, Jian 1 ; Duan, Shaorong 2 ; Zhang, Jing 4 ; Wang, Qi 1 ; Zhang, Yue 1 ; Li, Linge 1 ; Liu, Haitao 5 ; Xiao, Qingbo 6 ; Lin, Hongzhen 1 ;

作者机构： 1.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, iLab, Suzhou 215123, Peoples R China

2.Tsinghua Univ, State Key Lab Low Dimens Quantum Phys, Beijing 100084, Peoples R China

3.Tsinghua Univ, Dept Phys, Beijing 100084, Peoples R China

4.Xian Univ Technol, Sch Mat Sci & Engn, Xian 710048, Peoples R China

5.Inst Appl Phys & Computat Math, Lab Computat Phys, Beijing 100088, Peoples R China

6.Jiangsu Acad Agr Sci, Recycling Agr Res Ctr, Nanjing 210014, Peoples R China

7.Helmholtz Inst Ulm HIU, D-89081 Ulm, Germany

关键词： Lithium sulfur battery; Oxygen-vacant electrocatalyst; Polysulfide kinetics; Pouch cell; High areal mass loading

期刊名称：CHEMICAL ENGINEERING JOURNAL （ 影响因子：13.273； 五年影响因子：11.529 ）

ISSN： 1385-8947

年卷期： 2021 年 417 卷

页码：

收录情况： SCI

摘要： The development of lithium/sulfur batteries has been hindered by notorious shuttling effect and sluggish electrochemical conversion kinetics owing to high barrier of lithium ion transport behaviors. In this work, anionic oxygen vacancies in niobium oxide nanoparticle is fabricated on a high-conductive hierarchical porous nano-carbon as a sulfur anchor and lithium ion accelerator. As evidenced by optical coloration and electrochemical measurements, the oxygen-deficient electrocatalyst shows much stronger interaction ability to polysulfides and endows superior catalytic ability of propelling ion kinetics and facilitating the precipitation of Li2S. Theoretical simulations have also revealed that Nb-S bonds are formed when polysulfides interacts with AOV-Nb2O5-x catalyst. Consequently, the as-prepared sulfur cathode exhibits a high initial capacity of 1489 mA h g(-1), corresponding to the theoretical utilization of 89%, and a long life for 600 cycles at 1 C. Enhancing current rate to 5 C, a rate capacity of 899 mA h g(-1) is obtained, demonstrating rapid conversion kinetics. Impressively, even increasing the areal loading to 4.2 mg cm(-2) with the lean electrolyte, the pouch cell can still exhibit the initial areal capacity of 3.54 mA h cm(-2) at 0.343 mA cm(-2) and stabilize for several tens of cycles, providing the promise for fast-charge batteries.

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