Core-shell magnetic microspheres as heterogeneous catalyst for synthesis of benzimidazole
文献类型： 外文期刊
作者： Yang, Linyan 1 ; Chen, Lan 1 ; Guo, Jinwei 1 ; Li, Cun 1 ; Jin, Tianming 2 ;
作者机构： 1.Tianjin Agr Univ, Tianjin Key Lab Agr Anim Breeding & Hlth Husb, Coll Anim Sci & Vet Med, Tianjin, Peoples R China
2.Tianjin Acad Agr Sci, Tianjin 300392, Peoples R China
关键词： gamma-Fe2O3; core-shell; condensation reaction; catalytic activity
期刊名称：JOURNAL OF COORDINATION CHEMISTRY （ 影响因子：1.869； 五年影响因子：1.547 ）
ISSN： 0095-8972
年卷期： 2022 年 75 卷 1-2 期
页码：
收录情况： SCI
摘要： gamma-Fe2O3 was used to prepare gamma-Fe2O3@SiO2, gamma-Fe2O3@SiO2-NH2 and gamma-Fe2O3@SiO2-NH2-COOH nanoparticles. Core-shell modification of IRMOF3 was used to obtain gamma-Fe2O3@SiO2-NH2-COOH/IRMOF3 nanoparticles. gamma-Fe2O3@SiO2-NH2-COOH/IRMOF3 nanoparticles were modified by activated arginine (Arg), glycine (Gly) and lysine (Lys) to synthesize gamma-Fe2O3@SiO2-NH2-COOH/IRMOF3-Arg, gamma-Fe2O3@SiO2-NH2-COOH/IRMOF3-Gly and gamma-Fe2O3@SiO2-NH2-COOH/IRMOF3-Lys nanoparticles. The products were used as catalysts for condensation reactions of benzaldehyde and o-phenylenediamine. Infrared spectroscopy (IR), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) spectra were used for the characterization. gamma-Fe2O3@SiO2-NH2-COOH/IRMOF3-Gly nanoparticles showed outstanding catalytic effects as determined by a fluorescence spectrophotometer. In RP-HPLC spectra, the retention time of the reaction products was 2.458 min and 3.392 min. The results of the H-1 NMR (400 MHz, MeOH-d(6)) spectra showed gamma-Fe2O3@SiO2-NH2-COOH/IRMOF3-Gly nanoparticles to be more active. [GRAPHICS] .
- 相关文献
作者其他论文 更多>>
-
A novel recombinant adenovirus expressing apoptin and melittin genes kills hepatocellular carcinoma cells and inhibits the growth of ectopic tumor
作者：Wu, Jingqiao;Lan, Zhaoyu;Li, Xin;He, Jinling;Zhang, Dongchao;Jin, Tianming;Jin, Tianming;Wu, Jingqiao;Lan, Zhaoyu;Li, Xin;He, Jinling;Zhang, Dongchao;Zhang, Dongchao;Jin, Tianming
关键词：Recombinant adenovirus; Melittin; Apoptin; Hepatocellular carcinoma
-
Design of multi-epitope vaccine against porcine rotavirus using computational biology and molecular dynamics simulation approaches
作者：Zhu, Xiaochen;Wang, Xinyuan;Liu, Tingting;Zhang, Dongchao;Jin, Tianming;Zhang, Dongchao;Jin, Tianming
关键词：Porcine Rotavirus; Bioinformatics; Multi-epitope vaccine; Molecular dynamic simulation
-
Transcriptomics analysis reveals molecular mechanism of softening and cell wall polysaccharides-disassembling in peaches treated by flow microcirculation of sodium nitroprusside medium
作者：Zheng, Yanli;Duan, Lihua;Ran, Yalin;Chen, Lan;Tang, Yao;Li, Xihong;Zhang, Peng;Jia, Xiaoyu;Zhang, Peng;Jia, Xiaoyu;Jiang, Yunbin;Jia, Xiaoyu;Zhao, Zhiyong;Li, Ziqin
关键词：Peach fruit; Sodium nitroprusside atomization; Cell wall polysaccharides; RNA-sequencing; Softening
-
Ozone mitigates the flesh discoloration in response to 1-methylcyclopro-pene by promoting anthocyanin biosynthesis in postharvest nectarines
作者：Zheng, Yanli;Duan, Lihua;Wang, Haifen;Li, Wenhan;Pan, Na;Wang, Xiaodong;Liang, Fuhao;Li, Xihong;Jiang, Yunbin;Pan, Yanfang;Chen, Lan;Jia, Xiaoyu;Jiang, Yunbin;Chen, Lan;Jia, Xiaoyu;Yang, Xiangzheng;Jia, Xiaoyu;Jia, Xiaoyu
关键词：Nectarine fruit; 1-MCP; Ozone; Anthocyanins biosynthesis; Gene expression
-
Inhibition effect of Aspergillus niger and quality preservation of apple by in-package sterilization medium flow of circulating
作者：Zheng, Yanli;Ran, Yalin;Du, Meijun;Yuan, Junwei;Wang, Haifen;Li, Xihong;Jia, Xiaoyu;Zhang, Peng;Li, Jiangkuo;Jia, Xiaoyu;Chen, Lan;Zhao, Zhiyong
关键词：Apple; Aspergillus niger; Aerosolized antimicrobials; Fruit quality
-
Constant storage temperature delays firmness decreasing and pectin solubilization of apple during post-harvest storage
作者：Chen, Lan;Wang, Xiaodong;Yuan, Junwei;Li, Xihong;Chen, Lan;Pan, Yanfang;Jia, Xiaoyu;Wang, Xiaodong
关键词：
-
Automatic periodical SO2 fumigation improves the storage quality of tender ginger
作者：Jia, Xiaoyu;Li, Jiangkuo;Jia, Xiaoyu;Li, Jiangkuo;Jia, Xiaoyu;Liu, Haidong;Du, Meijun;Zheng, Yanli;Chen, Lan;Song, Jianxin;Tang, Xianpu;Li, Xihong
关键词：
