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Preparation and Thermal Stability of Brominated Natural Rubber from Latex

文献类型： 外文期刊

作者： Xue, Xinghua 1 ; Wu, Yaohui 1 ; Wang, Fengping 1 ; Ling, Jun 1 ; Fu, Xin 2 ;

作者机构： 1.Hainan Univ, Coll Mat & Chem Engn, Minist Educ, Key Lab Trop Biol Resources, Haikou 570228, Peoples R China

2.Chinese Acad Trop Agr Sci, Rubber Res Inst, Danzhou 571737, Peoples R China

关键词： bromination;rubber;natural rubber latex;stabilization;thermogravimetric analysis

期刊名称：JOURNAL OF APPLIED POLYMER SCIENCE （ 影响因子：3.125； 五年影响因子：2.754 ）

ISSN： 0021-8995

年卷期： 2010 年 118 卷 1 期

页码：

收录情况： SCI

摘要： The effects of pH value of reaction system, reaction time, reaction temperature, bromine concentration, and amount of potassium persulfate on the bromination reaction in the preparation of brominated natural rubber (BNR) from natural rubber latex were discussed. It has been found from the thermal analysis, that is, the thermal degradation of BNR in nitrogen is a two-step reaction, and 16% carbonide with a stable structure remained at 470-650 degrees C. The thermo-oxidative degradation of BNR in air is also a two-step reaction, and the percentage of degraded BNR reaches to nearly 100% at 600 degrees C. (c) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 118: 25 29, 2010

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